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ChemicalBook >> CAS DataBase List >>Bis(triphenylphosphine)nickel(II)chloride

Bis(triphenylphosphine)nickel(II)chloride

CAS No.
14264-16-5
Chemical Name:
Bis(triphenylphosphine)nickel(II)chloride
Synonyms
NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;phosphine)nickeL;Bis(triphenylphosphine)nick;bis(triphenylphosphine)nickle(II)
CBNumber:
CB8433158
Molecular Formula:
C36H30Cl2NiP2
Molecular Weight:
654.17
MDL Number:
MFCD00009592
MOL File:
14264-16-5.mol
MSDS File:
SDS
Last updated:2024-08-23 14:20:09

Bis(triphenylphosphine)nickel(II)chloride Properties

Melting point 250 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Crystals or Powder
color Dark green to dark gray
Water Solubility insoluble
Sensitive Hygroscopic
Exposure limits NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference 14264-16-5(CAS DataBase Reference)
EWG's Food Scores
NIST Chemistry Reference
EPA Substance Registry System

SAFETY

Risk and Safety Statements

Symbol(GHS)  sòng bạc tiền thậtLiên kết đăng nhậpsòng bạc tiền thậtLiên kết đăng nhập
GHS07,GHS08
Signal word  Danger
Hazard statements  H317-H350-H412
Precautionary statements  P201-P273-P280-P302+P352-P308+P313
Hazard Codes  T
Risk Statements  45-43-52/53-34-20/21/22
Safety Statements  53-36/37-45-60-36/37/39-26
RIDADR  3260
WGK Germany  3
RTECS  QR6170000
21
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
HS Code  29310095
NFPA 704
0
3 0

Bis(triphenylphosphine)nickel(II)chloride price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 237116 Bis(triphenylphosphine)nickel(II) dichloride synthesis grade 14264-16-5 10g $56.8 2025-03-01 Buy
Sigma-Aldrich 237116 Bis(triphenylphosphine)nickel(II) dichloride synthesis grade 14264-16-5 50g $106.8 2025-03-01 Buy
TCI Chemical B1571 Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) 14264-16-5 10g $43 2025-03-01 Buy
TCI Chemical B1571 Bis(triphenylphosphine)nickel(II) Dichloride >96.0%(T) 14264-16-5 100g $200 2025-03-01 Buy
Alfa Aesar 013930 Dichlorobis(triphenylphosphine)nickel(II), 98% 14264-16-5 10g $43.65 2025-03-01 Buy
Product number Packaging Price Buy
237116 10g $56.8 Buy
237116 50g $106.8 Buy
B1571 10g $43 Buy
B1571 100g $200 Buy
013930 10g $43.65 Buy

Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Uses,Production

Reaction

  1. Catalyst for hydrosilylation of styrene with diphenysilane
  2. Catalyst for carboxylation of various aryl chlorides and other derivatives
  3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
  4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
  5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
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Chemical Properties

dark green to dark grey crystals or powder

Uses

Coordination compund.

Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

Uses

suzuki reaction

Purification Methods

Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]

Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials

Global( 349)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12455 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 14934 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21698 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
AB PharmaTech,LLC
323-480-4688 United States 989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Wuhan Pengo Technology.,Ltd.
+86-27-81330736 +86-13628634921 sunny.w@boronicgroup.com CHINA 171 58

View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
sòng bạc tiền thậtLiên kết đăng nhập 2024-08-23 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
sòng bạc tiền thậtLiên kết đăng nhập 2024-04-17 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $200.00 / KG 1KG 99% 500t Shanghai Yunao International Trade Co., Ltd
sòng bạc tiền thậtLiên kết đăng nhập 2023-09-24 Bis(triphenylphosphine)nickel(II)chloride
14264-16-5
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
Dichlorobis(triphenyIphosphine)-nickel tributyl-phosphin compd. with nickelchloride Nickel(II) chloride bis(triphenylphosphine) Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride Phosphine, tributyl-, compound with nickel chloride (2:1) Dichlorobis(triphenylphosphine)nickel(Ⅱ) Dichlorobis(triphenylphosphine)nickel(II), 98+% Dichlorobis(triphehylphosphine)nickel(II) ,98% Bis(triphenylphosphine)nickel(II)chloride, 98% 10GR Bis(triphenylphosphine)nickel(II) chloride,98% (PPh3)2NiCl2 NSC 137147 BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORI Bis (triphenylphosphine) nickel chloride Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis Bis(triphenylphosphine)nickel(II) dichloride synthesis grade Bis(triphenylphosphine)nickel(II)chloride,(PPh3)2NiCl2 NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL BIS(TRIPHENYLPHOSPHINO)NICKEL(II) CHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE Bis(tri-N-butylphosphine)dichloronickel bis(triphenylphosphine)dichloro-nicke Bis(triphenylphosphine)dichloronickel Dichlorobis(triphenyIphosphine)-nickel(II) dichlorobis(triphenylphosphine)-nicke Nickel, bis(triphenylphosphine)dichloro- Nickel, dichlorobis(triphenylphosphine)- Phosphine, tributyl-, compd. with nickelchloride (2:1) bis(triphenylphosphine)nickle(II) Bis-(triphenylphosphino)-nickel chloride tributyl-phosphincompd.withnickelchloride(2:1) Bis(triphenylphosphine)nickel(II) chloride for synthesis TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE Bis(triphenylphosphine)nickel(II) chloride, 98+% Bis(triphenylphosphine)dichloronickel(II)~Dichlorobis(triphenylphosphine)nickel(II) Bis(triphenylphosphine)nickel(II)chloride,99% Dichloro bis (Triphenyl phosphine) Nickel catalyst Bis(triphenylphosphine)nick Bis(triphenylphosphine)nickel(II)chloride,NiCl2(PPh3)2 Dichlorobis(triphenylphosphine)nickel(II), 98%, for synthesis Bis(triphenylphosphine)nickel(II) Dichloride > (II) dichL phosphine)nickeL Bis(triphenylphosphine)nickel(II)chloride ISO 9001:2015 REACH NiCl2(PPh3)2 DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II) BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE Bis(triphenylphosphine)nickel dichloride Bis(triphenylphosphin)nickel(II)chlorid 14264-16-5 14262-16-5 NiCl2PC6H532 C36H30P2NiCl2 C38H32NiCl2 C36H305Cl2NiP2 C36H30Cl2NiP2
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