ChemicalBook >> CAS DataBase List >>4-Nitrophenylhydrazine
4-Nitrophenylhydrazine
- CAS No.
- 100-16-3
- Chemical Name:
- 4-Nitrophenylhydrazine
- Synonyms
- P-NITROPHENYLHYDRAZINE;4-Nitrophenylhydra;4-NITROPHEYLHYDRAZINE;p-Nitrophenylhydrazide;4-NITROPHENYLHYDRAZINE;4-NITROPHENYLHDYRAZINE;Benzeneethanol,5-iodo-;p-Hydrazinonitrobenzene;P-NitroPhneyl Hydrazine;4-NitrophenylHydrazineGr
- CBNumber:
- CB7124653
- Molecular Formula:
- C6H7N3O2
- Molecular Weight:
- 153.14
- MDL Number:
- MFCD00007579
- MOL File:
- 100-16-3.mol
Last updated:2024-05-04 15:16:22
Melting point | 156 °C (dec.)(lit.) |
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Boiling point | 276.04°C (rough estimate) |
Density | 1.00 |
refractive index | 1.6910 (estimate) |
storage temp. | Explosives area |
pka | 3.81±0.20(Predicted) |
color | Orange-red leaflets or needles |
Water Solubility | soluble in hot water |
Merck | 14,6624 |
BRN | 608107 |
CAS DataBase Reference | 100-16-3(CAS DataBase Reference) |
EWG's Food Scores | |
FDA UNII | |
NIST Chemistry Reference | |
EPA Substance Registry System |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07,GHS02 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H228-H317-H319-H335-H312-H315 | |||||||||
Precautionary statements | P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P264-P280-P305+P351+P338-P337+P313P-P210-P240-P241-P280-P370+P378-P280-P302+P352-P312-P322-P363-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P270-P301+P312-P330-P501 | |||||||||
Hazard Codes | F,Xn | |||||||||
Risk Statements | 5-11-22-36/37/38-43-21/22 | |||||||||
Safety Statements | 16-26-36/37/39-37/39-36 | |||||||||
RIDADR | UN 3376 4.1/PG 1 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | MV8225000 | |||||||||
F | 4.6 | |||||||||
Hazard Note | Flammable/Harmful | |||||||||
HazardClass | 4.1 | |||||||||
PackingGroup | I | |||||||||
HS Code | 29280000 | |||||||||
Toxicity | mmo-sat 2 mmol/L AEMIDF 44,801,82 | |||||||||
NFPA 704 |
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4-Nitrophenylhydrazine Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powdeUses
Analytical reagent (aldehydes, ketones).Uses
4-Nitrophenylhydrazine is a nitro substituted aryl hydrazine with potential anticancer activity. Irritant.Definition
ChEBI: A member of the class of phenylhydrazines that is phenylhydrazine substituted at the 4-position by a nitro group.General Description
4-Nitrophenylhydrazine is a orange-red leaflet or needles wetted with water. 4-Nitrophenylhydrazine will emit toxic oxides of nitrogen when heated to decomposition. 4-Nitrophenylhydrazine is slightly heavier than water and insoluble in water. 4-Nitrophenylhydrazine may be irritating to skin, eyes and mucous membranes. 4-Nitrophenylhydrazine may be toxic by ingestion. 4-Nitrophenylhydrazine may be explosive and sensitive to friction in the dry state. 4-Nitrophenylhydrazine is used as a reagent for ketones and aliphatic aldehydes.Reactivity Profile
4-NITROPHENYLHYDRAZINE is a powerful explosive. 4-Nitrophenylhydrazine can SELF-IGNITE in the presence of contaminants. Auto-ignition temperature may vary for 4-nitrophenylhydrazine similar to that of hydrazine which has an autoignition of as low as 74oC in contact with iron rust. Dangerous fire hazard or severe explosion can occur when exposed to heat, flame or oxidizing agents. Severe explosion may also occur by chemical reaction with alkali metals; BaO; CaO; K; Na; NH3; Cl2; chromates; CuO; Cu++ salts; F2; H2O2; iron rust; metallic oxides; PbO2;Ni; Ni(ClO4)2; HNO3; N2O; O2; liquid O2; K2Cr2O7; Na2Cr2O7; tetryl; zinc diamide; Zn(C2H5)2. Dangerous; when heated to decomposition 4-Nitrophenylhydrazine emits highly toxic nitrogen compounds; may explode by heat or chemical reaction. (Sax and Lewis, 1987) under Hydrazine p. 538-539.Health Hazard
Some are toxic and may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.Safety Profile
Poison by intraperitoneal route.Mutation data reported. When heated to decomposition itemits toxic fumes of NOx. See also NITROCOMPOUNDS OF AROMATIC HYDROCARBONSPurification Methods
Crystallise the hydrazine from EtOH. The hydrochloride has m 212o(dec) (from EtOH, also m 202-203o dec). [Beilstein 15 III 331, 15 IV 317.]4-Nitrophenylhydrazine Preparation Products And Raw materials
Raw materials
Preparation Products
5-Aminoindole
1-METHYL-5-NITRO-1H-INDOLE
5-Nitroindole
4-THIOPHEN-2-YLPHENYLAMINE
Ethyl 5-nitroindole-2-carboxylate
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100-16-3(4-Nitrophenylhydrazine)Related Search:
p-Nitrophenylacetonitrile
4-Nitrophenyl chloroformate
Sodium 3-nitrobenzenesulphonate
4-Nitrobenzaldehyde
4-Nitrophenylacetic acid
4-NITROPHENYLACETYLENE
4-Fluoronitrobenzene
4-Nitrobenzonitrile
3-Nitrobenzaldehyde
4-Nitrobenzeneethanol
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1-(4-NITROPHENYL)HYDRAZINE
(4-nitrophenyl)-hydrazin
(p-nitrophenyl)-hydrazin
Hydrazine, (4-nitrophenyl)-
Hydrazine, (p-nitrophenyl)-
Hydrazine,(4-nitrophenyl)-
p-Hydrazinonitrobenzene
p-Nitrophenylhydrazide
P-NitroPhneyl Hydrazine
4-NitrophenylHydrazineGr
P-NITROPHENYLHYDRAZINE,REAGENT
PARA-NITROPHENYLHYDRAZINE
4-NITROPHENYLHYDRAZINE (DRY WT), STABILIZED WITH >30% WATER
4-Nitrophenylhydrazine (base and/or unspecified salts)
4-NITROPHENYLHYDRAZINE CP 97%
4-NITROPHEYLHYDRAZINE
4-Nitrophenylhydrazine, 98% (dry wt), stab. with >30% water
p-NITROPHENYLHYDRAZINE extrapure AR
4-Nitrophenyl hydrazine, 98% (dry wt basis)
4-NITROPHENYLHYDRAZINE
4-NITROPHENYLHDYRAZINE
4-Nitrophenylhydra
4-NITROPHENYLHYDRAZINE, 97%, MOISTENED WITH >30% WATER
4-Nitrophenylhydrazine, moistened with >30% water
4-Nitrophenylhydrazine,98%
4-Nitrophenylhydrazine,95%,10-18% water added
##DISCONTINUED## 4-Nitrophenylhydrazine, 98% (dry wt), stab. with >30% water
##DISCONTINUED## 4-Nitrophenylhydrazine
4-Hydrazinonitrobenzene, 1-Hydrazino-4-nitrobenzene
4-Nitrophenylhydrazine, stabilized with 30% water
4-Nitrophenylhydrazine (wet with 30% water w/w)
4-Nitrophenylhydrazine, 97%, stabilized with 30% water
4-?Nitrophenylhydrazine(wetwith30%waterw/w),97%
4-Nitro phenyl hydrazine, GR 99%+
P-NITROPHENYLHYDRAZINE
Benzeneethanol,5-iodo-
Benzenesulfonylchloride,5-chloro-2-methoxy-5-methyl-
100-16-3
100-06-3
O2NC6H4NH2NH2
O2NC6H4NHNH2
NO2C6H4NHNH2
Hydrazines
Nitrogen Compounds
Organic Building Blocks
Building Blocks
Phenylhydrazine
HydrazinesDerivatization Reagents
Derivatization Reagents HPLC
Nitrogen Compounds
Organic Building Blocks
UV-VIS
Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes